Demonstration of the Surface-Effect on Chemical Properties of Finely Divided Particles
To start the experiment do the following:
- Prepare a 100 ml of 10-3 M AgNO3 solution and a 10 mL of 1 % trisodium citrate solution by dissolving AgNO3 and trisodium citrate, respectively, in deionized water.
- Take a 500 mL volume conical flask (by clicking on it) and pour 100 ml of 10-3 M AgNO3 solution into the flask.
- Place the beaker on a magnetic stirrer-cum-heater.
- Set the heater temperature to 100°C (by clicking on the Heater knob)
- Place a magnetic bar into the flask and set the stirrer to a medium speed.
- The solution is heated to boiling.
- When water in the flask starts boiling, to this solution add 10 mL of 1 % trisodium citrate drop by drop with the help of a clean dropper. Note down your observation.
- When the color change is steady, turn off the heater and stirrer and bring down the Ag colloid to the room temperature.
- Collect 5 mL of the Ag colloid in a test tube from the above flask.
- Add saturated HgCl2 solution dropwise to the test tube and shake the test tube gently. Note down your observation.